２０２４年
Kimura,Y.,Kanno,R.,Mori,K.,Matsuda,Y.,Seto,R.,Takenaka,S.,Mino,H.,Ohkubo,T.,Honda,M., Sasaki,C.Y.,Kishikawa,J.,Mitsuoka,K.,Mio,K.,Hall,M.,Purba,R,E.,Mochizuki,T.,Mizoguchi,A.,Humbel,M.B., Madigan,T.M.,Wang-Otomo,Z.,Tani,K."The Thermal-Stable LH1−RC Complex of a Hot Spring Purple
Bacterium Powers Photosynthesis with Extremely Low-Energy Near-
Infrared Light" Biochemistry (2025) 64,170−179
Teranishi,M.,Ito,M.,Huang,Z.,Nishiyama,Y.,Masuda,A.,Mino,H.,Tachibana,M.,Inada,T.,Ohno,K."Extremely Low-Frequency Electromagnetic Field (ELF-EMF) Increases Mitochondrial Electron Transport Chain Activities and Ameliorates Depressive Behaviors in Mice",Int. J. Mol. Sci.(2024),25,11315
２０２３年
Kosaki, S. and Mino, H.,"Molecular Structure Related to an S =5/2 High-Spin S2 State Manganese Cluster of Photosystem II Investigated by Q-Band Pulse EPR Spectroscopy",J. PHYS. CHEM. B. 127, 6441-6448.
Saito,K.Nishii,S.,Asada,M., Mino,H. and Ishikita H.” Insights into the protonation state and spin structure for the g=2 multiline EPR signal of the oxygen-evolving complex” PNAS nexus (2023), pgad244.
Mino, H."Outline of EPR Spectroscopy" in Analytical Techniques for the Elucidation of Protein Function (2022) Wiley (Eds. Suetake,I.,Sharma, R.K., Hojo,H)
Komeyama, M., Kanno,K., Mino,H., Yasuno,Y., Shinada,T., .Ito, T.and Hemmi, H.” A [4Fe-4S] cluster resides at the catalytic center of phosphomevalonate dehydratase, an enzyme responsible for the archaeal mevalonate pathway ”Front. Microbiol. 14: 1150353
２０２２年
Saito,K., Mino,H., Nishio, S. and Ishikita H.” Protonation structure of the closed-cubane conformation of the O2-evolving complex in photosystem II”
PNAS nexus (2022),1(5), pgac221.
Toda,T., Ito,M., Takeda,J., Masuda, A, Mino, H., Hattori, N., Mohri, K. and Ohno, K.” Extremely low-frequency pulses of faint magnetic field, weaker than the geomagnetic field, induce mitophagy to rejuvenate mitochondria” Commun. Biol. (2022) 5,453.
Mino,H.” Temperature dependence of the formation of the g ~ 5 EPR signal in the oxygen evolving complex of photosystem II” Photosyn. Res. (2022) 152, pp.207-212
Mino, H. and Asada M.," Location of two Mn2+ affinity sites in photosystem II detected by pulsed electron–electron double resonance", Photosyn. Res. (2022) 152, 289–295.
２０２１年
三野広幸 ”パルスESR法を用いたタンパク質の構造、相互作用解析”, NMRによる有機材料分析とその試料前処理、データ解釈 技術情報協会 (2021)
Trinh, M, Miyazaki D., Ono, S., Nomata, J., Kono, M., Mino, H., Niwa, T., Okegawa, Y., Motohashi, K., Taguchi, K,, Hisabori, T., and Masuda, S. “The Evolutionary Conserved Iron-Sulfur Protein TCR Controls P700 Oxidation in Photosystem I”, iScience (2021) 24,102059.
２０２０年
Taguchi,S.,Shen, L., Han,G., Umena, Y.,Shen, J-R., Noguchi,T., and Mino,H.," Formation of the High-Spin S2 State Related to the Extrinsic Proteins in the Oxygen Evolving Complex of Photosystem II" , J. Phys.Chem. Lett (2020) 11, 8908-8913.
Taguchi, S., Noguchi, T. and Mino, H. ," Molecular Structure of the S2 State with a g = 5 Signal in the Oxygen Evolving Complex of Photosystem II" , J. Phys.Chem. B (2020) 124, 5531-5537.
Mino, H. and Nagashima, H. ," Orientation of Ligand Field for Dangling Manganese in Photosynthetic Oxygen-Evolving Complex of Photosystem II" , J. Phys.Chem. B (2020) 124, 128-133
２０１８年
Tsukuno,H., Ozeki, K., Kobayashi,I., Hisatomi, O. and Mino, H.,"Flavin Radical Formation in the Light-Oxygen-Voltage-sensing Domain of the Photozipper Blue-light Sensor Protein, J. Phys.Chem. B (2018) 122, 8819-8823.
Nagashima, H. and Mino, H. ”Local structural modification of Ca2+-depleted Photosystem II detected by proton matrix ENDOR” Applied Magnetic Resonance (2018) 8, 652-625s.
Asada, M., Nishimura, T., Ifuku, K. and Mino, H.” Location of the Extrinsic Subunit PsbP in Photo-system II Studied by Pulsed Electron-Electron Double Resonance”, Biochim. Biophys. Acta, (2018) 1859, 394-399.
Ozeki, K., Tsukuno,H.,Nagashima, H., Hisatomi, O. and Mino, H "Dimeric Structure of the Blue Light Sensor Protein Photozipper in the Active State" Biochemistry,(2018)57,494-497.
Nagashima, H.,Asada, M. and Mino, H " Magnetic Structure of Manganese Cluster in Photosystem II Investigated by Electron Paramagnetic Resonance" Biophys. Physicobiology,(2018)15,45-50.
２０１７年
Zavafer, A., Koinuma, W., Chow, S. W., Cheah, H. M. and Mino, H. ”Mechanism of Photodamage of the Oxygen Evolving Mn Cluster of Photosystem II by Excessive Light Energy” Sci. Rep.,(2017)7,7604.
Nagashima,H., Kishimoto, H., Mutoh, R., Terashima, N., Oh-oka,H., Kurisu, G.and Mino, H.,"Hyperfine Sublevel Correlation Spectroscopy Studies of Iron-Sulfur Cluster in Rieske Protein from Green Sulfur Bacterium Chlorobaculum tepidum" J. Phys.Chem. B, (2017) ,121, 2543-2553
Hasegawa,M., Nagashima, H., Minobe, R., Tachikawa,T., Mino,H. and Kobori,Y., “Regulated Electron Tunneling of Photoinduced Primary Charge- Separated State in the Photosystem II Reaction Center” J. Phys.Chem. Lett., (2017) 8, 1179–1184. DOI: 10.1021/acs.jpclett.7b00044
Nagashima,H. and Mino, H. “Location of Methanol on the S2 State Mn Cluster in Photosystem II Studied by Proton Matrix Electron Nuclear Double Resonance” J. Phys.Chem. Lett., (2017) 8, 621-625
浅田瑞枝、長嶋宏樹、三野広幸, 生物物理 57, 1-4 (2017), ESR分光法による光化学系IIの酸素発生系Mnクラスターの構造解析 生物物理 57, 1-4 (2017)
２０１５年
Nagashima,H., Nakajima, Y., Shen, J-R. and Mino, H. ” Proton matrix ENDOR studies on Ca2+-depleted and Sr2+-substituted Mn cluster in photosystem II” J. Biol. Chem., (2015) 290, 28166-28174
Asada, M and Mino, H. "Location of the High-Affinity Mn2+ Site in Photosystem II Detected by PELDOR" J. Phys. Chem. B.,(2015) 119 (32), 10139-10144
２０１４年
Isobe,H., Shoji,M., Yamanaka,S., Mino, H., Umena,Y., Kawakami,K., Kamiya,N., Shen,J.-R. and Yamaguchi, K.” Generalized approximate spin projection calculations of effective exchange integrals of the CaMn4O5 cluster in the S1 and S3 states of the oxygen evolving complex of photosystem II”
Phys. Chem. Chem. Phys., (2014) 16,11911-119123
Ishii,K.,Terauchi,S.,Murakami, R., Swain, J.V., Mutoh, R., Mino. H., Maki, K., Arata, T. and Ishiura, M. “Site-directed spin labeling-electron spin resonance mapping of the residues of cyanobacterial clock protein KaiA that are affected by KaiA–KaiC interaction” Genes to Cells (2014) 19, 297-324
２０１３年
Nagashima, H. and Mino, H. “Highly resolved proton matrix ENDOR of oriented Photosystem II membranes in the S2 state” Biochim. Biophys. Acta (2013) 1827, 1165-1173
Asada, M., Nagashima, H., Koua, F. H. M., Shen, J.-R., Kawamori, A. and Mino, H. “Electronic structure of S2 state of the oxygen-evolving complex of photosystem II studied by PELDOR” Biochim. Biophys. Acta (2013) 1827, 438-445
２０１２年
Akai, M., Onai,K., Morishita, M., Mino, H., Shijuku, T., Maruyama, H., Arai, F., Itoh, S., Hazama, A., Checchetto, V., Szabo, I., Yukutake, Y., Suematsu, M., Yasui, M., Ishiura, M. and Uozumi, N,"Aquaporin AqpZ is Involved in Cell Volume Regulation and Sensitivity to Osmotic Stress in Synechocystis sp. PCC 6803" J. Biol. Chem. (2012)194, 6828-6836
２０１１年
Asada,Y., Mutoh, R., Ishiura, M. and Mino, H. ” Nonselective excitation of pulsed ELDOR using multi-frequency microwaves” Journal of Magnetic Resonance, (2011) 213, 200-205.
Kondo, T., Masuda, S. and Mino, H. ”Pulsed EPR analysis of the photo-induced triplet radical pair in the BLUF protein SyPixD: Determination of the protein-protein distance and orientation in the oligomeric protein” Applied Magnetic Resonance (2011) 40,545-555.
Mutoh, R., Mino, H., Murakami, R., Uzumaki, T. and Ishiura, M. “Thermodynamically induced conformational changes of the cyanobacterial circadian clock protein KaiB" Applied Magnetic Resonance (2011) 40, 525-535.
Tsuno, M., Suzuki, H., Kondo, T., Mino, H. and Noguchi, T ” Interaction and Inhibitory Effect of Ammonium Cation in the Oxygen Evolving Center of Photosytem II” Biochemistry (2011) 50, 2506-2514
Mito, F., Yamasaki, T., Ito, Y., Yamato,M., Mino, H., Sadasue,H., Shirahama,C., Sakai,K., Utsumi, H. and Yamada, K. “Monitoring the Aggregation Processes of Amyloid-ß Using a Spin-Labeled, Fluorescent Nitroxyl Radical” Chem. Commun. (2011) 47, 5070–5072
Kondo, T., Masuda, S., Tsutsui, K. and Mino, H. “Temperature dependence of relaxation time of a stable radical pair in SyPixD investigated by pulsed EPR” Chem. Phys. Lett. (2011) 501,528-533
２０１０年
Zhou, Z., Hashimoto, Y., Cui, T., Washizawa, Y., Mino, H. and Kobayashi, M. “Unique Biogenesis of High-molecular-mass Multimeric Metalloenzyme Nitrile Hydratase: Intermediates, and a Proposed Mechanism for Self-Subunit Swapping Maturation” Biochemistry (2010) 49,9638-9648
Ishigure, S., Mitsui,T., Ito,S., Kondo, Y., Kawabe, S., Kondo, M., Dewa,T., Mino,H., Itoh, S. and Nango, M.” Peroxide Decoloration of CI Acid Orange 7 Catalyzed by Manganese Chlorophyll Derivatives at the Surfaces of Micelles and Lipid Bilayers” Langmuir (2010) 26, 7774-7782
Mutoh, R., Mino, H., Murakami, R., Uzumaki,T., Takabayashi, A. Ishii, K. and Ishiura, M. “Direct interaction between KaiA and KaiB revealed by a site-directed spin labeling electron spin resonance analysis” Genes to Cells (2010) 15, 269–280
２００９年
Yui,T., Tsuchino,T., Mino,H., Kajino,T., Itoh,S., Fukushima,Y. and Takagi, K.” Remarkably Stabilized Charge Separations in Inorganic Nanospace” Bull. Chem. Soc. Jpn. (2009)Vol. 82, No. 7, 914–916,
Tsukatani, Y., Nakayama, N., Shimada, K, Mino, H., Itoh, S., Matsuura, K., Hanada, S., Nagashima, KVP “Characterization of a blue-copper protein, auracyanin, of the filamentous anoxygenic phototrophic bacterium Roseiflexus castenholzii” ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS (2009) 490, 57-62
２００８年
Nagai, H. and Fukushima, Y., Okajima, K., Ikeuchi, M and Mino, H. ”Formation of interacting spins on flavosemiquinone and tyrosine radical in photoreaction of a blue light sensor BLUF protein TePixD” Biochemistry (2008) 47, 12574-12582
Mino, H. and Kawamori, A. “The difference in microenvironments and functions of tyrosine radicals YZ and YD in photosystem II studied by EPR” Photosyn. Res. (2008) 98,151–157
Miyamoto, R., Mino, H., Kondo, T., Itoh,, S., Oh-oka, H.” An Electron Spin-Polarized Signal of the P800+A1(Q)− State in the Homodimeric Reaction Center Core Complex of Heliobacterium modesticaldum” Biochemistry (2008) 47, 4386-4393.
２００７年
Itoh, S., Mino, H., Itoh, K., Shigenaga, T., Uzumaki, T. and Iwaki, M. “Function of chlorophyll d in reaction centers of photosystems I and II of the oxygenic photosynthesis of Acaryochloris marina”, Biochemistry (2007) 46,12473-12481.
Yamada,H., Mino, H. and Itoh, S. ” Protons in the vicinity of Mn cluster in photosystem II oxygen evolving complex studied by proton matrix ENDOR”, Biochim. Biophys. Acta (2007) 1767, 197-203.
２００６年
Matsuoka, H., Furukawa,K., Kato, T., Mino, H., Shen, J.R. Kawamori, A. "g-Anisotropy of the S2-State Manganese Cluster in Single Crystals of Cyanobacterial Photosystem II Studied by W-Band EPR Spectroscopy" The Journal of Physical Chemistry, (2006) 110, 13242-13247.
Miyamoto, R., Iwaki, M., Mino,H., Harada, J., Itoh, S. and Oh-oka, H. “ESR signal of the iron-sulfer center FX and its function in the homodimeric reaction center of Heliobacterium modesticaldum” Biochemistry, (2006) 45, 6306-6316.
Katayama,Y., Hashimoto,K., Nakayama, H., Mino,H. Nojiri,M. Ono,T. Nyunoya,H. Yohda,M. Takio,K. and Odaka, M. Thiocyanate hydrolase is a cobalt-containing metalloenzyme with a cysteine sulfinic acid ligand“ J. Am. Chem. Soc. USA. (2006)128,729-730
２００５年
Mino, H., Kawamori, A. Aoyama, D. Tomo, T., Iwaki, M. and Itoh, S.
“Proton ENDOR spectroscopy of the primary donor P740+ made of a chlorophyll d special pair in photosystem I reaction center of Acaryochloris marina” Chem. Phys. Lett. (2005) 411, 262-266
Mino, H. and Itoh, S.
“EPR properties of a g = 2 broad signal trapped in S1 state in the Ca2+-depleted Photosystem II” Biochm. Biophys. Acta.(2005) 1708, 42-49.
Mino, H. and Itoh, S.
“The Origin of the split signals in the Ca2+-depleted PS II” Photosynthesis Research (2005) 84, 333-337
2004年以前
Itoh, T., Yano, K., Kajino, T., Itoh, S., Shibata, Y., Mino,H., Miyamoto, R., Inada, Y. Iwai, S. and Fukushima, Y. “Nanoscale Organization of Chlorophyll a in Mesoporous Silica: Efficient Energy Transfer and Stabilized Charge Separation as in Natural Photosynthesis J. Phys. Chem. B (2004) 13683, 108, 13683-13687
Mino, H. and Ono, T.
“Applications of pulsed ELDOR detected NMR measurements to studies of Photosystem II: Magnetic characterization of YD tyrosine radical and Mn2+ bound to the high-affinity site” Applied Magnetic Resonance (2003) 23, 571-584
Mino, H., Ishii, A. and Ono, T.
“Nonlinear relationship between g=2 doublet and multiline signals in Ca2+-depleted Photosystem II” Biochim. Biophys. Acta (2003) 1606, 127-136
Kawamori, A. Katsuta, N. Mino, H., Ishii,A., Minagawa, J. and Ono, T.-A.
“Position of QA and ChlZ Relative to YZ and YD in Photosytem II Studied by Pulsed EPR”
J. Biol. Phys. (2002) 28, 413-426.
Dzuba, S. A., Kawamori, A., Katsuta, N., Hara, H., Mino, H. and Itoh, S.,
“Spin relaxation of a spin-correlated radical pair P700+A1- in the PS I photosynthetic reaction center” Chem. Phys. Lett. (2002) 362, 307-313.
Ono, T., Rompel, A., Mino, H. and Chiba, N.
“Ca2+ Function in Photosynthetic Oxygen Evolution studied by Alkali Metal cation Substitution”,
Biophysical Journal (2001) 81, 1831-1840.
Mino, H., Kawamori, A and Ono, T.
“Pulsed EPR studies of doublet signal and singlet-like signal in oriented Ca2+-depleted PS II membranes: location of the doublet signal center in PS II” Biochemistry (2000) 39, 11034-11040
Mino, H., Kawamori, A. and Ono, T.
“pH-dependent characteristics of YZ radical in Ca2+-depleted Photosystem II studied by CW EPR and pulsed ENDOR” Biochim. Biophys. Acta (2000) 1457, 157-165.
Onoda, K., Mino, H., Inoue, Y. and Noguchi, T.
“An FTIR study on the structure of the oxygen-evolving Mn-cluster of Photosystem II in different spin forms of the S2 state” Photosynthesis research (2000) 63, 47-57.
Ono, T and Mino, H
“Unique binding Site for Mn2+ ion responsible for Reducing an Oxidized YZ Tyrosine in Manganese-Depleted Photosystem II membranes” Biochemistry (1999) 38,8778-8785.
Matsukawa, T., Mino H., Yoneda D. and Kawamori, A.
“Dual-Mode EPR Study of New Signals from the S3-state of Oxygen-Evolving Complex in Photosystem II” Biochemistry (1999) 38, 4072-4077
Matsukawa, T., Kawamori, A. and Mino, H.
“Electron paramagnetic resonance study of the magnetic structure of the S1-statein oriented oxygen evolving photosystem membranes” , Spectrochimica Acta. Part A (1999) 55, 895-901
Mino, H, Kawamori, A., Matsukawa, T. and Ono, T.
“Light-induced high-spin signals from the oxygen evolving center (OEC) in Ca2+-depleted Photosystem II studied by dual mode EPR spectroscopy”, Biochemistry (1998) 37, 2794-2799.
Mino, H., Astashkin, A.V. and Kawamori, A.
“An EPR and Pulsed ENDOR Study of the Structure of Tyrosine Z• in Mn-depleted Photosystem II.” Spectrochimica Acta. Part A (1997) 53, 1465-1483
Astashkin, A.V. Mino, H., Kawamori, A. and Ono, T. “Pulsed EPR study of S3' signal in the Ca2+-depleted Photosystem II” Chem. Phys. Lett. (1997) 272, 506-516
Yamauchi, T., Mino, H., Matsukawa, T., Kawamori, A. and Ono, T.
“Parallel Polarization Electron Paramagnetic resonance Studies of the S1-state Manganese Cluster in the Photosynthetic Oxygen-Evolving system.”, Biochemistry (1997) 36,7520-7526.
Shigemori, K., Mino, H. and Kawamori, A.
“pH and Temperature Dependence of Tyrosine Z• Decay Kinetics in Tris-Treated PS II Particles Studied by Time-Resolved EPR.” Plant and Cell Physiology (1997) 38, 1007-1011.
Mino, H and Kawamori, A.
“Microenvironments of tyrosine D+ and tyrosine Z+ in Photosystem II studied by proton matrix ENDOR” , Biochim. Biophys. Acta (1994) 1185, 213-220
Mino, H., Satoh, J. Kawamori, A., Toriyama, K and Zimmermann, J-L.
“Matrix ENDOR of tyrosine D+ in oriented Photosystem II membranes”, Biochim. Biophys. Acta (1993) 1144, 426-433
国際会議proceedings
Itoh, S., Fukushima, Y., Itoh, K., Maeda, M., Mino, H. and Kumazaki, S.
“Photosystem I and II reaction centers in a new type oxygenic photosynthesis of Acaryochloris marina based on chlorophyll d: studies of delayed fluorescence and triplet state ESR”
J. Photoscience (2002) 9(2), 70-73.
Kawamori, A., Katsuta, N., Arao, S., Hara, H., Mino, H., Ishii, A., Ono, T., Minagawa, J.
“Configuration of electron transfer cofactors in photosystem II studied by pulsed EPR” J. Photoscience (2002) 9(2), 379-381
Mino, H. and Itoh, S.
“ORIGIN OF THE g=2 BROAD EPR SIGNAL IN THE Ca2+-DEPLETED PS II IN S1 STATE” Photosynthesis Fundamental Aspects to Global Perspective (2005) 350-352
Mino, H. and Ono, T.,
“Application of pulsed ELDOR detected NMR measurements on the studies of photosystem II”, in “EPR in the 21st century”(2002), pp684-687, Elsevier.
Mino. H., Ono. T. and Kawamori. A.
“THE EPR STUDY OF TYROSINE-Z AND MANGANESE CLUSTER IN THE Ca2+-DEPLETED PHOTOSYSTEM II” Photosynthesis: Mechanisms and Effects, vol II,1407- 1410, (1998) Kluwer Academic Publishers, Netherlands.
Kawamori, A., Matsukawa, T. and Mino, H.
“DUAL MODE EPR STUDY OF S3-STATE MANGENESE CLUSTER IN THE OXYGEN EVOLVING PHOTOSYSTEM II” Photosynthesis: Mechanisms and Effects, vol II,1331-1334, (1998) Kluwer Academic Publishers, Netherlands.
Mino, H., Astashkin, A.V., Kawamori, A., Ono, T. and Inoue, Y.
“THE LOW PH FORM OF REDOX-ACTIVE COMPONERNTS IN THE DONOR SIDE OF PHOTOSYSTEM II STUDIED BY PULSED EPR AND ENDOR"
Photosynthesis: from Light to Biosphere, vol I,559-562, (1995) Kluwer Academic Publishers, Netherlands.
Kawamori, A., Mino, H., Astashkin. A.V., Kuroiwa, S. and Akabori, K.
“ESEEM AND PULSED ENDOR STUDIED OF PROMARY ACCEPTOR QUINONE IN PHOTOSYSTEM II.” Photosynthesis: from Light to Biosphere, vol. I, 563-566, (1995) Kluwer Academic Publishers, Netherlands.
Mino, H., Kodera, Y. and Kawamori, A.
“DIFFERENCE IN ENVIRONMENTS OF TYROSINE-Z AND TYROSINE-D STUDIED BY PROTON MATRIX ENDOR” Research in Photosynthesis, Volume II, 61-64, (1992) Kluwer Academic Publishers, Netherlands.
Kodera, Y., Takura, K., Mino, H. and Kawamori, A.
“PULSED EPR STUDY OF TYROSINE-Z+ IN PHOTOSYSTEM II"
Research in Photosynthesis, Volume II,57-60, (1992) Kluwer Academic Publishers, Netherlands.
総説
Mino, H. and Kawamori, A. “EPR studies of the water oxidizing complex in the S1 and the higher S-states: the manganese cluster and YZ radical”, Biochim. Biophys. Acta 1503 (2001) 112-122.
三野広幸“ENDOR法の発展とその応用” 分光研究 第55巻 第２号 110-116
（2006年）
著書
光合成辞典 ５項目執筆（日本光合成研究会編、学会出版センター ２００３年）
光合成研究法 ＥＳＲの項目を執筆（日本光合成研究会編、２００９年）